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Dr. Nicolas Vogt

Research focus
Cyclometallated nickel complexes as catalysts for C-C-crosscoupling reactions - Synthesis and (spectro)electrochemical properties

Cyclic voltammetry

Analytical methods
NMR-, UV/Vis-Spectroscopy
Cyclic voltammetry
EPR spectroscopy
DFT calculation
Single crystal XRD

Dissertation (May 2018)
Neuartige Cyclometallierte Komplexe des Nickels mit Carbanionischen Konjugierten Triaren-CNN-Liganden

Master thesis (April 2014)
Manganese and Iron Complexes as Catalysts for the Oxidative Deconstruction of Lignin Model Compounds


“Co-ligand Involvement in Cyclometalated Nickel Complexes [(Phbpy)Ni(X)] (PhbpyH = 6-phenyl-2,2’-bipyridine) X = F, Cl, Br, I, and CnFm”, N. Vogt­­, A. Sandleben, M. T. Chin, S. Yu, D. A. Vicic, A. Klein*, Inorg. Chem. 2018, Manuskript in Arbeit.

“Novel Cyclometalated Nickel Complexes [(R-Phbpy)Ni(Br)] (HPhbpy = 6-phenyl-2,2’-bipyridine) – Substituent Effects on Redox Behaviour and Stability”, A. Sandleben, N. Vogt, M. T. Chin, D. A. Vicic, A. Klein*, Organometallics 2018, Manuskript eingereicht.

“Reductive transformation of V(III) precursors into vanadium(II) oxide nanowires”, O. Ojelere, D. Graf, T. Ludwig, N. Vogt, A. Klein, S. Mathur, Dalton Trans. 2018, 47, 6842-6849. DOI: 10.1039/c8dt00848e

“Nickel-alkyl complexes with a reactive PNC-pincer ligand”, L. S. Jongbloed, N. Vogt, A. Sandleben, B. de Bruin, A. Klein, J. I. van der Vlugt, Eur. J. Inoig. Chem. 2018, 2408–2418. DOI: 10.1002/ejic.201800168

“Nitrogen–Nitrogen Bond Formation via a Substrate-Bound Anion at a Mononuclear Nickel Platform”, M. D. Kosobokov, A. Sandleben, N. Vogt, A. Klein,  D. A. Vicic, Organometallics 2018, 37, 521-525. DOI: 10.1021/acs.organomet.7b00887

“Novel Cyclometalated Nickel(II) Complexes: Stability, Spectroelectrochemical Properties, and Application as Catalysts in C–C-Coupling Reactions”, Vortrag auf der 14. Koordinationschemietagung, Mär. 2018 in Heidelberg.

“Unsymmetrical N-aryl-1-(pyridin-2-yl)methanimine ligands in organonickel(II) complexes – more than a blend of 2,2’-bipyridine and N,N-diaryl--diimines?”, C. Biewer, C. Hamacher, A. Kaiser, N. Vogt, A. Sandleben, M. T. Chin, S. Yu, D. A. Vicic, A. Klein* Inorg. Chem. 2016, 55, 12716-12727. DOI: 10.1021/acs.inorgchem.6b01874

“Synthesis, structure and reactivity of cyclometalated nickel(II) complexes – a review and perspective” A. Klein,* A. Sandleben, N. Vogt, Proc. Nat. Acad. Sci. India (PNASI) Section-A; Physical Sciences 2016, 86(4), 533-549. DOI 10.1007/s40010-016-0289-6

“Redoxchemistry of Cyclometalated Nickel Complexes carrying Phenylbipyridine Ligands and Halido or Perfluorophenyl Coligands - DFT backed (Spectro)electrochemical Measurements”, N. Vogt, A. Klein, Poster auf der 12. Koordinationschemietagung, Feb. 2016 in Kiel.

“Cyclometallated Ni(II) Complexes Carrying Anionic Tridentate Phenylbipyridine-Ligands and Halido or Perfluoroaryl Coligands”, N. Vogt, A. Klein, Poster auf der International Chemical Conference of the Pacific Basis Societies (PacifiChem), Dez. 2015 in Honolulu., Hawaii, USA.

“Derivatives of the Cyclometallated Nickel(II) Complex [(Phbpy)NiBr] (Phbpy = 6-(Phen-2-yl)-2,2’-bipyridine) – Synthesis, Spectroscopic and Electrochemical Studies”, A. Sandleben, N. Vogt, A. Klein, Poster auf der 11. Koordinationschemietagung, Mär. 215 in Paderborn.

“The Cyclometalated Nickel Complex [(Phbpy)NiBr] (Phbpy = 2,2’-bipyridine-6-phen-2-yl) – Synthesis, Spectroscopic and Electrochemical studies”, A. Klein,* B. Rausch, A. Kaiser, N. Vogt, A.. Krest J. Organomet. Chem. 2014, 774, 86-93. DOI: 10.1016/j.jorganchem.2014.10.013